CONVERSION OF POLYOLEFINS TO LIGHT OLEFINS WITH BASE-METAL HETEROGENOUS CATALYSTS

Tech ID: 33508 / UC Case 2024-108-0

Patent Status

Patent Pending

Brief Description

The disposal and recycling of polyolefins (like polyethylene and polypropylene) present a significant environmental and economic challenge, as current recycling methods are often costly and energy-intensive, or result in lower-value products. UC Berkeley researchers have developed innovative methods for converting polyolefins into valuable light olefins such as propylene and isobutylene. This innovation uses base-metal heterogeneous catalysts to convert polyethylene into propylene and a C3 to C30 alkene, and to convert polypropylene into a high-yield mixture of propylene and isobutylene. A key advantage of this method is the ability to achieve high conversion yields at significantly lower reaction temperatures compared to existing technologies, offering a more efficient and sustainable route to upcycle plastic waste into high-demand chemical feedstocks.

Suggested uses

Production of high-value chemical building blocks (propylene, isobutylene) from waste plastics (polyethylene, polypropylene) for use in the chemical industry.
Sustainable, lower-carbon alternative for the chemical industry to source propylene and isobutylene, which are typically derived from fossil fuels.
Integration into plastic recycling infrastructure to convert difficult-to-recycle polyolefin streams into usable feedstocks.

Advantages

 High yield conversion of polyolefins to desirable light olefins (propylene, isobutylene).

Operation at lower reaction temperatures than existing thermal or catalytic methods, resulting in reduced energy costs.

Utilization of base-metal heterogeneous catalysts, which are typically less expensive and more readily available than precious-metal catalysts.
Offers a chemically distinct and superior approach to upcycling polyolefin plastic waste.

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Inventors

  • Hartwig, John F.

Other Information

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