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pH Signaling and Regulation in Pyridinium Redox Flow Batteries

The implementation of cost-effective and reliable energy storage solutions, such as redox flow batteries, is often hindered by the complexity and expense of accurately monitoring their state of charge (SOC) and state of health (SOH). To address this, a novel approach using low-cost management systems and methods has been developed for electrochemical cells based on viologen, particularly pyridinium redox flow batteries. This innovation centers on pH signaling and regulation to enable real-time SOC and SOH monitoring. The viologen species' electrochemical processes naturally induce localized pH changes, and by monitoring and regulating the pH within the cell, researchers can obtain immediate, actionable data on the battery's operating condition. This pH-based system offers a simple, integrated, and economical alternative to conventional, often more complex, monitoring techniques.

Quasi-Molecular Nano-Dielectric Designs For Efficient Particle-Based Photocatalysis

A novel theoretical model enables efficient and cost-effective solar-driven water splitting to generate clean, storable hydrogen fuel.

Photocatalyst Suspension Reactor for Solar Water Splitting

A novel reactor design that enables cost-effective green hydrogen production via solar water splitting, targeting $1/kg-H2 at scale.

Spiral Wound Interfacial Reactors For Separation And Resource Recovery

      The widespread occurrence of nutrient-rich and metal-contaminated wastewater presents an environmental challenge and untapped economic opportunity. Ammonia, copper, and phosphorous are prime targets. For example, ammonia is industrially produced by the Haber-Bosch process, a highly energy-intensive (~12.5 kWh/kg-N to convert N2 to ammonia, consuming 1-2% of global energy usage) and greenhouse gas-emitting (~1.2% of global CO2 emissions) technique. After use, primarily as fertilizer, nearly 50% of all U.S.-consumed ammonia ends up in municipal wastewater and animal feedlot retention systems. Technologies presently proposed for recovering critical nutrients and metals from wastewater are limited in scalability by high energy demands, costly chemicals or membrane requirements, low efficiencies, or fouling challenges.       UC Berkeley researchers have developed and demonstrated a low-cost, robust, and near-zero-energy reactor that simultaneously recovers ammonia and other valuable ions (e.g., P and Cu) from wastewater streams. The reactor is driven by sunlight or low-grade waste heat, such that it eliminates the need for external pumping—further cutting energy consumption and capital cost. The functional material is an inexpensive cloth that is also roll-to-roll compatible, making it economically scalable and easy to manufacture. The reactor can be implemented within wastewater streams including municipal wastewater, animal feedlot wastewater, and organic waste digestate. It may further be adapted to recover other valuable resources, such as lithium, from sources like mining wastewater and landfill leachate. It may even be extended beyond nutrient and metal recovery to separation or pre-concentration of volatile organic compounds such as ethanol and methanol from aqueous solutions.

Enabling Partial Soft-Switching Within Regulating Switched Capacitor Converter

High-conversion-ratio power converters used in compact Point-of-Load (PoL) applications, such as data centers or portable electronics, often face the challenge of large size and weight due to the necessary energy-storage components, particularly flying capacitors, while also struggling with switching losses that reduce efficiency. This innovation, developed by UC Berkeley researchers, addresses these issues with a novel regulating hybrid switched-capacitor (HSC) power converter topology referred to as a "Dual Inductor Switching Bus Converter" (DISB converter). The DISB converter combines an initial 2:1 switched-capacitor conversion stage with a Symmetric Dual-Inductor Hybrid (SDIH) conversion stage, capitalizing on the benefits of both. The initial 2:1 voltage reduction significantly reduces the overall volume and weight of the flying capacitors, while the SDIH stage contributes a reduced component count and an excellent switch stress figure of merit. Crucially, a proposed auxiliary circuit block enables near-zero-voltage conditions (partial soft-switching) within the initial 2:1 stage, which significantly improves the converter's overall efficiency.

Current-Programmed Modulation of Flying Capacitor Multilevel Converters

Flying Capacitor Multilevel Converters (FCMLCs) are widely used in high-power applications, but they present significant control challenges, particularly in maintaining stable and balanced voltages across the numerous flying capacitors while achieving continuous and fast output voltage regulation. This innovation, developed by UC Berkeley researchers, discloses a novel current-programmed modulator with smooth bin transitions that inherently addresses these challenges. The modulator achieves continuous full-range output voltage regulation and, critically, fast flying-capacitor voltage-balancing dynamics . By programming the current and ensuring smooth transitions between the modulator's operational bins, the technology overcomes the limitations of traditional control methods, resulting in a more reliable, efficient, and robust converter topology suitable for demanding high-power applications.

Electrochemical Production of Calcium Hydroxide for Cement Manufacturing

Revolutionizing cement manufacturing through an energy-efficient electrochemical method that produces calcium hydroxide with reduced CO2 emissions.

PGM-free Materials for Oxygen Evolution Reaction in PEM Electrolyzers

An innovative approach to stabilize non-precious metal catalysts for enhanced efficiency and durability in PEM electrolyzers.

Electrospun Iridium Oxide/Nafion Electrodes for PEM Water Electrolysis

This technology introduces a novel method of producing high-efficiency, durable electrodes for polymer electrolyte membrane water electrolysis (PEMWE) using electrospinning.

Solarshare: Community-Centered Energy Sharing For Energy-Resilient Urban Neighborhoods

Urban neighborhoods face increasing energy vulnerability due to power grid disruptions and unequal access to renewable energy. The SolarShare framework, developed by UC Berkeley researchers, addresses this by providing a community-centered approach to enhance urban energy resilience through decentralized renewable energy networks. SolarShare facilitates optimized energy sharing networks, leading to a significant increase in renewable energy accessibility and cost reduction, while demonstrably strengthening community resilience against power disruptions, offering a highly adaptable and scalable solution superior to traditional centralized or less-optimized decentralized systems.

Synthesis of Robust Oxygen Evolution Electrocatalysts from Calixarene-templated

Oxygen Evolution Reaction (OER) is crucial for various renewable energy applications, but current electrocatalysts often face issues with stability, efficiency, and cost. This invention addresses these challenges by introducing a novel method for synthesizing robust oxygen evolution electrocatalysts. The technology, developed by UC Berkeley researchers, utilizes calixarene-templated iridium compositions. This approach yields highly stable and efficient electrocatalysts, offering significant advantages over traditional iridium-based catalysts. Specifically, this innovation provides superior performance and durability, making it a valuable tool for energy systems like electrolyzers and fuel cells.

Multilayered Iridium Oxide Catalyst For Oxygen Evolution Reaction

This technology introduces a novel electrocatalyst design that significantly improves stability and activity for oxygen evolution reaction (OER) in acidic environments.

Integrated Seawater Air Conditioning And Seaweed Cultivation System For Sustainable Energy And Resource Recovery

The increasing global energy demands and the need for sustainable practices present an opportunity for integrated systems that offer both energy efficiency and resource recovery. This Integrated Seawater Air Conditioning and Seaweed Cultivation System for Sustainable Energy and Resource Recovery addresses these challenges by utilizing the typically wasted cold deep-sea water effluent from a Seawater Air Conditioning (SWAC) system to support the cultivation of seaweed. The SWAC system itself provides highly efficient, low-energy cooling by circulating cold deep-sea water through a heat exchanger to chill a closed-loop coolant.

Isothermal Carbon Capture And Release Of Carbon Dioxide With Molecular Polyamines

The problem of carbon dioxide (CO2​) emissions from industrial processes and mixed gas streams presents a significant global challenge, often addressed by energy-intensive and costly technologies. UC Berkeley researchers have developed an innovative solution for capturing and removing CO2​ in an energy-efficient, isothermal manner. The invention is a novel composition that uses a porous organic framework of solid molecular hexamine, specifically 2,3,6,7,14,15-hexakis(aminomethyl)triptycene, that assembles into a three-dimensional ammonium carbamate network. This unique network possesses two one-dimensional pores that selectively capture CO2​ upon exposure. This technology enables the capture and subsequent release of CO2​ without the large temperature or pressure swings required by conventional methods, offering a more sustainable and economically viable approach to carbon management.

Spectral Kernel Machines With Electrically Tunable Photodetectors

       Spectral machine vision collects both the spectral and spatial dependence (x,y,λ) of incident light, containing potentially useful information such as chemical composition or micro/nanoscale structure.  However, analyzing the dense 3D hypercubes of information produced by hyperspectral and multispectral imaging causes a data bottleneck and demands tradeoffs in spatial/spectral information, frame rate, and power efficiency. Furthermore, real-time applications like precision agriculture, rescue operations, and battlefields have shifting, unpredictable environments that are challenging for spectroscopy. A spectral imaging detector that can analyze raw data and learn tasks in-situ, rather than sending data out for post-processing, would overcome challenges. No intelligent device that can automatically learn complex spectral recognition tasks has been realized.       UC Berkeley researchers have met this opportunity by developing a novel photodetector capable of learning to perform machine learning analysis and provide ultimate answers in the readout photocurrent. The photodetector automatically learns from example objects to identify new samples. Devices have been experimentally built in both visible and mid-infrared (MIR) bands to perform intelligent tasks from semiconductor wafer metrology to chemometrics. Further calculations indicate 1,000x lower power consumption and 100x higher speed than existing solutions when implemented for hyperspectral imaging analysis, defining a new intelligent photodetection paradigm with intriguing possibilities.

Nonlinear Microwave Impedance Microscopy

      Microwave impedance microscopy (MIM) is an emerging scanning probe technique that enables non-contact, nanoscale measurement of local complex permittivity. By integrating an ultrasensitive, phase-resolved microwave sensor with a near-field probe, MIM has made significant contributions to diverse fundamental and applied fields. These include strongly correlated and topological materials, two-dimensional and biological systems, as well as semiconductor, acoustic, and MEMS devices. Concurrently, notable progress has been made in refining the MIM technique itself and broadening its capabilities. However, existing literature has focused exclusively on linear MIM based on homodyne architectures, where reflected or transmitted microwave is demodulated and detected at the incident frequency. As such, linear MIM lacks the ability to probe local electrical nonlinearity, which is widely present, for example, in dielectrics, semiconductors, and superconductors. Elucidating such nonlinearity with nanoscale spatial resolution would provide critical insights into semiconductor processing and diagnostics as well as fundamental phenomena like local symmetry breaking and phase separation.       To address this shortcoming, UC Berkeley researchers have introduced a novel methodology and apparatus for performing multi-harmonic MIM to locally probe electrical nonlinearities at the nanoscale. The technique achieves unprecedented spatial and spectral resolution in characterizing complex materials. It encompasses both hardware configurations enabling multi-harmonic data acquisition and the theoretical and calibration protocols to transform raw signals into accurate measures of intrinsic nonlinear permittivity and conductivity. The advance extends existing linear MIM into the nonlinear domain, providing a powerful, versatile, and minimally invasive tool for semiconductor diagnostics, materials research, and device development.

CO2 Upgrading into C2 Oxygenates with a CuAg Tandem Electrocatalyst

The challenge in carbon dioxide utilization is efficiently converting it into valuable, multi-carbon chemicals. Current carbon dioxide electroreduction methods often suffer from low selectivity and yield towards desirable products like two-carbon oxygenates, such as ethanol and acetate, which are key platform molecules for the chemical industry. This innovation, developed by UC Berkeley researchers, addresses this by using a novel Copper-Silver (CuAg) tandem electrocatalyst within a membrane electrode assembly (MEA) cell to efficiently upgrade carbon dioxide into two-carbon oxygenates. This technology offers significantly enhanced selectivity and efficiency for two-carbon oxygenate production directly from carbon dioxide compared to conventional single-metal or mixed-metal catalysts, presenting a more sustainable and economically viable route for chemical synthesis.

Bent Crystal Spectrometer For Pebble Bed Reactor Burnup Measurement

      Pebble bed reactors (PBRs) are an emerging advanced nuclear reactor design where fuel pebbles constantly circulate through the core, as opposed to housing static fuel assemblies, generating numerous advantages including the ability for online refueling versus expensive shutdowns. Online refueling is overall beneficial but poses an operation challenge in that the pebbles must be measured and analyzed for burnup characteristics very quickly (in under 40 seconds), without much time to cool down, challenging the high Purity Germanium (HPGe) detectors historically used for burnup measurements. HPGe detectors can normally only be operated up to tens of thousands of counts per second, far below radiation rates from freshly discharged fuel, and are therefore operated at large distances from sources, with significant shielding. Only a small fraction of detected counts comes from burnup markers, yielding high uncertainty, or can be completely masked by effects of Compton scattering within the detectors.      To overcome the challenges of using HGPe detectors to measure burnup in continuously fueled reactors, UC Berkeley researchers have developed a novel technology capable of measuring gamma rays within a fine energy ranges and without the interference of Compton scattering. The device is also significantly cheaper than HPGe detectors and offers a reduced detector footprint. Nuclides including but not limited to Np-239, Eu-156, and Zr-95 can be measured and analyzed for burnup, path information through the core, and fast and thermal fluence. Furthermore, precise measurement of the Np-239 content provides better data for reactor safeguard purposes. The technology offers meaningful improvements in measurement accuracy, footprint, and cost, for PBRs and other continuously fueled reactors, such as molten salt reactors (MSRs).

Palladium Based Catalyst For Co2 Reduction With High Co Tolerance

An innovative Palladium hydride catalyst that significantly enhances the electroreduction of carbon dioxide (CO2) to formate with exceptional tolerance for carbon monoxide (CO).

Production Of Cementitious Materials Using Microwave Induced Plasma Heating

Cement manufacturing is an energy-intensive process, traditionally requiring high-temperature kilns, which contributes significantly to industrial energy consumption and emissions. This innovation, developed by UC Berkeley researchers, presents a novel, energy-efficient method for producing cementitious materials.

Droplet Hotspot Cooling Due To Thermotaxis

      Effective thermal management remains a critical challenge in designing and operating next-generation electronics, data centers, and energy systems. Devices are steadily shrinking and handling increased power densities. Traditional cooling strategies, such as heat sinks and immersive cooling systems, fall short in delivering the targeted, localized cooling needed to prevent or address thermal hotspots. Current solutions for localized hotspot cooling require active, energy-intensive methods like pumping of coolants and complex thermal architecture design.       To overcome these challenges, UC Berkeley researchers present a transformative passive method for localized, autonomous cooling of hotspots. The cooling system delivers effective, localized cooling across various device surfaces and geometries, including those geometries wherein cooling media must move against gravity. The benefits of the present system will be appreciated for computer chip and other electronics cooling, microgravity applications, battery thermal management. Beyond thermal management, the underlying system may also open novel avenues in fluid manipulation and energy harvesting.

Piezoelectric Transformers For Power Conversion

      The demand for miniaturized power electronics with increased efficiency and performance motivates the exploration of piezoelectric structures as alternative passive components; piezoelectric components store energy in mechanical compliance and inertia with extremely high quality factors and energy densities significantly greater than those of magnetics at small scales. Recent magnetic-less dc-dc converter designs based on single-port piezoelectric resonators (PRs) have demonstrated power stage efficiencies of 99% and PR power handling densities of up to 5.7 kW/cm3. While marking tremendous milestones, such performance has only been achieved in non-isolated dc-dc converters with mild (2:1) voltage conversion ratios, confining the utility of piezoelectric-based power conversion to a narrow subset of applications.       Piezoelectrics may be expanded to a broader set of applications through use of multi-port piezoelectric transformers (PTs), which offer the same advantages as PRs but with the added potential for galvanic isolation and inherent voltage transformation. The present invention overcomes standing performance shortcomings in isolated magnetic-less PT-based dc-dc converters, providing a framework for high-efficiency piezoelectric transformer (PT) designs (wherein isolated PTs serve as the primary passive components in isolated dc-dc converters). One of the proposed PT designs is validated in a dc-dc power converter prototype and demonstrates a peak efficiency of 97.5%. The measured performance represents a 17x reduction in loss ratio compared to previous isolated magnetic-less PT-based dc-dc converter designs, and expands the value of piezoelectrics to applications requiring isolation.

Thin Film Thermophotovoltaic Cells

Researchers at the University of California, Davis (“UC Davis”) have developed an optical absorber/emitter for thermophotovoltaics application with a tunable emission wavelength.

Solar-to-Hydrogen Reactor Design

An innovative reactor design that converts sunlight into hydrogen fuel efficiently and cost-effectively.

Mechanical Power Generation Through Passive Radiative Cooling

Researchers at the University of California, Davis have developed an approach to generating mechanical power from the earth's ambient thermal radiation using a Stirling engine.

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