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Electrochemical Production of Calcium Hydroxide for Cement Manufacturing

Revolutionizing cement manufacturing through an energy-efficient electrochemical method that produces calcium hydroxide with reduced CO2 emissions.

PGM-free Materials for Oxygen Evolution Reaction in PEM Electrolyzers

An innovative approach to stabilize non-precious metal catalysts for enhanced efficiency and durability in PEM electrolyzers.

Electrospun Iridium Oxide/Nafion Electrodes for PEM Water Electrolysis

This technology introduces a novel method of producing high-efficiency, durable electrodes for polymer electrolyte membrane water electrolysis (PEMWE) using electrospinning.

Multilayered Iridium Oxide Catalyst For Oxygen Evolution Reaction

This technology introduces a novel electrocatalyst design that significantly improves stability and activity for oxygen evolution reaction (OER) in acidic environments.

Spectral Kernel Machines With Electrically Tunable Photodetectors

       Spectral machine vision collects both the spectral and spatial dependence (x,y,λ) of incident light, containing potentially useful information such as chemical composition or micro/nanoscale structure.  However, analyzing the dense 3D hypercubes of information produced by hyperspectral and multispectral imaging causes a data bottleneck and demands tradeoffs in spatial/spectral information, frame rate, and power efficiency. Furthermore, real-time applications like precision agriculture, rescue operations, and battlefields have shifting, unpredictable environments that are challenging for spectroscopy. A spectral imaging detector that can analyze raw data and learn tasks in-situ, rather than sending data out for post-processing, would overcome challenges. No intelligent device that can automatically learn complex spectral recognition tasks has been realized.       UC Berkeley researchers have met this opportunity by developing a novel photodetector capable of learning to perform machine learning analysis and provide ultimate answers in the readout photocurrent. The photodetector automatically learns from example objects to identify new samples. Devices have been experimentally built in both visible and mid-infrared (MIR) bands to perform intelligent tasks from semiconductor wafer metrology to chemometrics. Further calculations indicate 1,000x lower power consumption and 100x higher speed than existing solutions when implemented for hyperspectral imaging analysis, defining a new intelligent photodetection paradigm with intriguing possibilities.

Nonlinear Microwave Impedance Microscopy

      Microwave impedance microscopy (MIM) is an emerging scanning probe technique that enables non-contact, nanoscale measurement of local complex permittivity. By integrating an ultrasensitive, phase-resolved microwave sensor with a near-field probe, MIM has made significant contributions to diverse fundamental and applied fields. These include strongly correlated and topological materials, two-dimensional and biological systems, as well as semiconductor, acoustic, and MEMS devices. Concurrently, notable progress has been made in refining the MIM technique itself and broadening its capabilities. However, existing literature has focused exclusively on linear MIM based on homodyne architectures, where reflected or transmitted microwave is demodulated and detected at the incident frequency. As such, linear MIM lacks the ability to probe local electrical nonlinearity, which is widely present, for example, in dielectrics, semiconductors, and superconductors. Elucidating such nonlinearity with nanoscale spatial resolution would provide critical insights into semiconductor processing and diagnostics as well as fundamental phenomena like local symmetry breaking and phase separation.       To address this shortcoming, UC Berkeley researchers have introduced a novel methodology and apparatus for performing multi-harmonic MIM to locally probe electrical nonlinearities at the nanoscale. The technique achieves unprecedented spatial and spectral resolution in characterizing complex materials. It encompasses both hardware configurations enabling multi-harmonic data acquisition and the theoretical and calibration protocols to transform raw signals into accurate measures of intrinsic nonlinear permittivity and conductivity. The advance extends existing linear MIM into the nonlinear domain, providing a powerful, versatile, and minimally invasive tool for semiconductor diagnostics, materials research, and device development.

Bent Crystal Spectrometer For Pebble Bed Reactor Burnup Measurement

      Pebble bed reactors (PBRs) are an emerging advanced nuclear reactor design where fuel pebbles constantly circulate through the core, as opposed to housing static fuel assemblies, generating numerous advantages including the ability for online refueling versus expensive shutdowns. Online refueling is overall beneficial but poses an operation challenge in that the pebbles must be measured and analyzed for burnup characteristics very quickly (in under 40 seconds), without much time to cool down, challenging the high Purity Germanium (HPGe) detectors historically used for burnup measurements. HPGe detectors can normally only be operated up to tens of thousands of counts per second, far below radiation rates from freshly discharged fuel, and are therefore operated at large distances from sources, with significant shielding. Only a small fraction of detected counts comes from burnup markers, yielding high uncertainty, or can be completely masked by effects of Compton scattering within the detectors.      To overcome the challenges of using HGPe detectors to measure burnup in continuously fueled reactors, UC Berkeley researchers have developed a novel technology capable of measuring gamma rays within a fine energy ranges and without the interference of Compton scattering. The device is also significantly cheaper than HPGe detectors and offers a reduced detector footprint. Nuclides including but not limited to Np-239, Eu-156, and Zr-95 can be measured and analyzed for burnup, path information through the core, and fast and thermal fluence. Furthermore, precise measurement of the Np-239 content provides better data for reactor safeguard purposes. The technology offers meaningful improvements in measurement accuracy, footprint, and cost, for PBRs and other continuously fueled reactors, such as molten salt reactors (MSRs).

Palladium Based Catalyst For Co2 Reduction With High Co Tolerance

An innovative Palladium hydride catalyst that significantly enhances the electroreduction of carbon dioxide (CO2) to formate with exceptional tolerance for carbon monoxide (CO).

Piezoelectric Transformers For Power Conversion

      The demand for miniaturized power electronics with increased efficiency and performance motivates the exploration of piezoelectric structures as alternative passive components; piezoelectric components store energy in mechanical compliance and inertia with extremely high quality factors and energy densities significantly greater than those of magnetics at small scales. Recent magnetic-less dc-dc converter designs based on single-port piezoelectric resonators (PRs) have demonstrated power stage efficiencies of 99% and PR power handling densities of up to 5.7 kW/cm3. While marking tremendous milestones, such performance has only been achieved in non-isolated dc-dc converters with mild (2:1) voltage conversion ratios, confining the utility of piezoelectric-based power conversion to a narrow subset of applications.       Piezoelectrics may be expanded to a broader set of applications through use of multi-port piezoelectric transformers (PTs), which offer the same advantages as PRs but with the added potential for galvanic isolation and inherent voltage transformation. The present invention overcomes standing performance shortcomings in isolated magnetic-less PT-based dc-dc converters, providing a framework for high-efficiency piezoelectric transformer (PT) designs (wherein isolated PTs serve as the primary passive components in isolated dc-dc converters). One of the proposed PT designs is validated in a dc-dc power converter prototype and demonstrates a peak efficiency of 97.5%. The measured performance represents a 17x reduction in loss ratio compared to previous isolated magnetic-less PT-based dc-dc converter designs, and expands the value of piezoelectrics to applications requiring isolation.

Thin Film Thermophotovoltaic Cells

Researchers at the University of California, Davis (“UC Davis”) have developed an optical absorber/emitter for thermophotovoltaics application with a tunable emission wavelength.

Solar-to-Hydrogen Reactor Design

An innovative reactor design that converts sunlight into hydrogen fuel efficiently and cost-effectively.

Mechanical Power Generation Through Passive Radiative Cooling

Researchers at the University of California, Davis have developed an approach to generating mechanical power from the earth's ambient thermal radiation using a Stirling engine.

High Power Density Electrochemical Energy Conversion Devices

This invention significantly enhances the power density of fuel cells through precise nanoscale control of the catalyst layer and the introduction of novel catalytic materials.

Microporous Layer/Catalyst Layer Integration For Electrolyzers

This invention combines the attributes of existing catalyst layer architectures to optimize reactions in solid polymer membrane electrolyzers.

Compact Catadioptric Mapping Optical Sensor For Parallel Goniophotometry

      Goniophotometers measure the luminance distribution of light emitted or reflected from a point in space or a material sample. Increasingly there is a need for such measurements in real-time, and in real-world situations, for example, for daylight monitoring or harvesting in commercial and residential buildings, design and optimization of greenhouses, and testing laser and display components for AR/VR and autonomous vehicles, to name a few. However, current goniophotometers are ill-suited for real-time measurements; mechanical scanning goniophotometers have a large form factor and slow acquisition times. Parallel goniophotometers take faster measurements but suffer from complexity, expense, and limited angular view ranges (dioptric angular mapping systems) or strict form factor and sample positioning requirements (catadioptric angular mapping systems). Overall, current goniophotometers are therefore limited to in-lab environments.      To overcome these challenges, UC Berkeley researchers have invented an optical sensor  for parallel goniophotometry that is compact, cost-effective, and capable of real-time daylight monitoring. The novel optical design addresses key size and flexibility constraints of current state-of-the-art catadioptric angular mapping systems, while maximizing the view angle measurement at 90°. This camera-like, angular mapping device could be deployed at many points within a building to measure reflected light from fenestrations, in agricultural greenhouses or solar farms for real-time monitoring, and in any industry benefitting from real-time daylight data.

Computational Framework for Numerical Probabilistic Seismic Hazard Analysis (PSHA)

      Probabilistic Seismic Hazard Analysis (PSHA) has become a foundational method for determining seismic design levels and conducting regional seismic risk analyses for insurance risk analysis, governmental hazard mapping, critical infrastructure planning, and more. PSHA traditionally relies on two computationally intensive approaches: Riemann Sum and conventional Monte Carlo (MC) integration. The former requires fine slices across magnitude, distance, and ground motion, and the latter demands extensive synthetic earthquake catalogs. Both approaches become notably resource intensive for low-probability seismic hazards, where achieving a COV of 1% for a 10−4 annual hazard probability may require 108 MC samples.       UC Berkeley researchers have developed an Adaptive Importance Sampling (AIS) PSHA, a novel framework to approximate optimal importance sampling (IS) distributions and dramatically reduce the number of MC samples to estimate hazards. Efficiency and accuracy of the proposed framework have been validated against Pacific Earthquake Engineering Research Center (PEER) PSHA benchmarks covering various seismic sources, including areal, vertical, and dipping faults, as well as combined types. Seismic hazards are calculated up to 3.7×104 and 7.1×103 times faster than Riemann Sum and traditional MC methods, respectively. Coefficients of variation (COVs) are below 1%. Enhanced “smart” AIS PSHA variants are also available that outperform “smart” implementations of Riemann Sum by a factor of up to 130.

Active Inductor Based On A Piezoelectric Resonator

      Miniaturization and performance of power electronics is fundamentally limited by magnetic components, whose power densities inherently reduce at small scales. Piezoelectric resonators (PRs), which store energy in the mechanical compliance and inertia of a piezoelectric material, offer various advantages for power conversion including high quality factors, planar form factors, opportunity for batch fabrication, and potential for integration. Contrary to magnetic components, PRs have increased power handling densities at small scales. Noteworthy advancements have been made in magnetic-less, PR-based power converter designs, demonstrating significant achievements in both power density (up to 5.7 kW/cm3) and efficiency (up to >99%). However, while PRs are promising alternative passive components, they cannot be used as drag-and-drop replacements for magnetics; achieving high performance in a PR-based converter requires complicated control of multi-stage switching sequences. A need exists for more practical ways to leverage piezoelectrics in power conversion without such added complexity.      To address this challenge, UC Berkeley researchers have developed a piezoelectric component that may be leveraged to directly emulate the dynamics of a magnetic component. The “active inductor” can serve as a drag-and-drop replacement for bulky magnetic inductors in power converters. Power density and efficiency of underlying piezoelectrics are preserved while the design complexity associated with piezoelectric-based power converters is simplified. Detailed models and control strategies for the piezoelectric-based active inductors have been developed and usage demonstrated in a classic buck converter. The active inductor is further validated with closed-loop simulation results and open-loop experimental results, confirming its inductor-like behavior.

Additives For Improved Electrochemical Co2 Capture

Current methods for CO2­ ­capture and concentration (CCC) are energy intensive due to the reliance on thermal cycles, which are intrinsically Carnot limited in efficiency. Electrochemical carbon dioxide capture and concentration (eCCC) is a modular approach that can achieve significantly higher energy efficiencies than current thermal methods, however eCCC systems have been plagued by oxygen instability. The Yang lab has developed an eCCC approach that is over three times more efficient than any other reported redox carrier-based system and almost twice the efficiency of state-of-the-art alkanolamine-based systems.

Digital Meter-On-Chip with Microfluidic Flowmetry

Researchers at the University of California, Davis have developed a microfluidic flowmetry technology that achieves on-chip measurement with ultrahigh precision across a wide tunable range.

Silicon Solar Cells that Absorb Solar Photons Above 2.2 eV and are Transparent to Solar Photons Below 2.2 eV

Traditionally, land can be used for either crop growth or energy production. This technology optimizes the efficiency of land use by combining both. Researchers at the University of California, Davis have developed solar cell designs that absorb only specific solar photons (> 2.2 eV) to create electricity, while letting through beneficial light (< 2.2 eV) for efficient crop growth.

Multi-Dimensional Computer Simulation Code For Proton Exchange Membrane (Pem) Electrolysis Cell (Ec) Advanced Design And Control

Polymer electrolyte membrane (PEM) electrolyzers have received increasing attention for renewable hydrogen production through water splitting. In order to develop such electrolyzers, it is necessary to understand and model the flow of liquids, gases, and ions through the PEM. An advancedmulti-dimensional multi-physics model is established for PEM electrolyzer to describe the two-phase flow, electron/proton transfer, mass transport, and water electrolysis kinetics.

Multi-channel ZULF NMR Spectrometer Using Optically Pumped Magnetometers

         While nuclear magnetic resonance (NMR) is one of the most universal synthetic chemistry tools for its ability to measure highly specific kinetic and structural information nondestructively/noninvasively, it is costly and low-throughput primarily due to the small sample-size volumes and expensive equipment needed for stringent magnetic field homogeneity. Conversely, zero-to-ultralow field (ZULF) NMR is an emerging alternative offering similar chemical information but relaxing field homogeneity requirements during detection. ZULF NMR has been further propelled by recent advancements in key componentry, optically pumped magnetometers (OPMs), but suffers in scope due to its low sensitivity and its susceptibility to noise. It has not been possible to detect most organic molecules without resorting to hyperpolarization or 13C enrichment using ZULF NMR.         To overcome these challenges, UC Berkeley researchers have developed a multi-channel ZULF spectrometer that greatly improves on both the sensitivity and throughput abilities of state-of-the art ZULF NMR devices. The novel spectrometer was used in the first reported detection of organic molecules in natural isotopic abundance by ZULF NMR, with sensitivity comparable to current commercial benchtop NMR spectrometers. A proof-of-concept multichannel version of the ZULF spectrometer was capable of measuring three distinct chemical samples simultaneously. The combined sensitivity and throughput distinguish the present ZULF NMR spectrometer as a novel chemical analysis tool at unprecedented scales, potentially enabling emerging fields such as robotic chemistry, as well as meeting the demands of existing fields such as chemical manufacturing, agriculture, and pharmaceutical industries.

High-Precision Chemical Quantum Sensing In Flowing Monodisperse Microdroplets

      Quantum sensing is rapidly reshaping our ability to discern chemical processes with high sensitivity and spatial resolution. Many quantum sensors are based on nitrogen-vacancy (NV) centers in diamond, with nanodiamonds (NDs) providing a promising approach to chemical quantum sensing compared to single crystals for benefits in cost, deployability, and facile integration with the analyte. However, high-precision chemical quantum sensing suffers from large statistical errors from particle heterogeneity, fluorescence fluctuations related to particle orientation, and other unresolved challenges.      To overcome these obstacles, UC Berkeley researchers have developed a novel microfluidic chemical quantum sensing device capable of high-precision, background-free quantum sensing at high-throughput. The microfluidic device solves problems with heterogeneity while simultaneously ensuring close interaction with the analyte. The device further yields exceptional measurement stability, which has been demonstrated over >103s measurement and across ~105 droplets.  Greatly surpassing the stability seen in conventional quantum sensing experiments, these properties are also resistant to experimental variations and temperature shifts. Finally, the required ND sensor volumes are minuscule, costing only about $0.63 for an hour of analysis. 

Electrically Fueled Active Supramolecular Materials

Invention of a new platform for creating active supramolecular materials using electrical energy as the fuel.

Organoaluminum Flow Battery Analytes

Researchers at the University of California, Davis, have developed an improved redox flow battery (RFB) for intermittent renewable energy applications such as wind, solar, and tidal. The device provides high-density energy storage and transfer without losing capacity over time and frequent replacement as with traditional lithium batteries.

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