Synthesis of materials inside templates has emerged as a useful and versatile technique to generate three-dimensional nanostructures. Previous approaches use templates consisting of microporous membranes, zeolites, and crystalline colloidal arrays. These have been used to construct elaborate electronic, mechanical, or optical structures. Porous Si is an attractive candidate as a template because the porosity and average pore size can be readily tuned by adjustment of the electrochemical preparation conditions. Additionally, elaborate 2- and 2.5-dimentional photonic crystals are readily prepared in porous Si.
Researchers at UC San Diego have demonstrated the templating of solution-cast and injection molded thermoplastic organic, inorganic, and biopolymers in porous Si multilayer (Rugate, Bragg filter) structures. The castings retain the photonic structure of the template. Demonstrated uses of the castings include vapor sensors, deformable and tunable optical filters, as well as self-reporting, bioresorbable drug-delivery materials.
This technology is available for licensing.
Country | Type | Number | Dated | Case |
United States Of America | Issued Patent | 7,713,778 | 05/11/2010 | 2003-024 |